David van Gerven
Contact
Contact
Institute of Inorganic Chemistry
Greinstr. 6
Office 405
50939
Telephone +49 221 470 76409
Fax +49 221 470 5083
E-mail david.vangerven(at)uni-koeln.de
Additional Information
Links
Research area
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Sophisticated reactions with sulfur trioxide (SO3)
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Structural characterization and spectroscopic analysis of strong acids and their corresponding salts
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In situ crystallization and structural analysis using an Optical Heating and Crystallization Device (OHCD)
Teaching
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Experiments as part of the lecture MN-C-AlC (General Chemistry)
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Design and maintenance of digital learning materials on the university platform ILIAS
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Experiments as part of the lecture (MN-C-AC) (Inorganic Chemistry)
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Experiments as part of the Childrens University Unsere Luft – ein tolles Gasgemisch!
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Lecture (MN-A-AC)
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Supervision of final theses (Bachelor’s and Master’s theses)
PhD (Dr. rer. nat.), University of Cologne, July 2020
SO3 als Reaktionsmedium: Synthese und Charakterisierung neuer Sulfatderivate [Link]
Master’s thesis, University of Oldenburg, June 2015
Neuartige (Disulfato)-metallate: Synthese, Struktur und Eigenschaften
Bachelor’s thesis, University of Oldenburg, AK Martens, January 2013
Sequentielle Multikomponenten- und Aza-Wittig-Reaktion zur Synthese neuer Heterocyclen
Publications
- A. Mertens, K. Eppers, D. van Gerven, M. S. Wickleder
The Molecular Structures of Lithium Trichlate, Li[Cl3CSO3]∙2H2O, and Lithium Tribrate, Li[Br3CSO3]∙2H2O
Eur. J. Inorg. Chem. 2024, , ejic.202400060.
10.1002/ejic.202400060 - A. Mertens, D. van Gerven, H. Lee, M. S. Wickleder
Synthesis and Characterization of the Trichlates [N(CH3)4][Cl3CSO3], [NH4][Cl3CSO3], and the Dichlate [NH4][Cl2CHSO3]
Eur. J. Inorg. Chem. 2024, 27, e202300535.
10.1002/ejic.202300535 - A. Mertens, K. Eppers, D. van Gerven, M. S. Wickleder
Triflate's bigger brother: The unprecedented tribrate anion, [Br3CSO3]−
Chem. Eur. J. 2024, e202303617.
10.1002/chem.202303617 - F. Hartl, V. Brune, S. Lüggert, C. Hegemann, D. van Gerven, M. Wilhelm, S. Ji, H. Choi, S. Mathur
Direct Synthesis of Two-Dimensional SnSe and SnSe2 through Molecular Scale Preorganization
Inorg. Chem. 2023, 62, 6274-6287.
10.1021/acs.inorgchem.2c04083 - A. E. L. Cammiade, L. Straub, D. van Gerven, M. S. Wickleder, U. Ruschewitz
Synthesis, Structure, and Spectroscopic Properties of Luminescent Coordination Polymers Based on the 2,5-Dimethoxyterephthalate Linker
Chemistry 2023, 5, 965-977.
10.3390/chemistry5020065 - A. Mertens, D. van Gerven, I. Kunert, M. S. Wickleder
Trichlates, an Unattended Class of Compounds: Characterization of Cl3CSO2Cl, and (H5O2)[Cl3CSO3]
Chem. Eur. J. 2023, 29, e202302128.
10.1002/chem.202302128 - T. Kasperowicz, D. van Gerven, M. S. Wickleder
The Cyanido-Sulfate Anion [SO3CN]−
Chem. Eur. J. 2023, 29, e202301761.
10.1002/chem.202301761 - V. Zimmermann, L. V. Schindler, D. van Gerven, M. S. Wickleder
The reaction of NH4Cl with SO3: Two modifications of (NH4)[SO3Cl]
Zeitschrift für anorganische und allgemeine Chemie 2022, 648, e202200238.
10.1002/zaac.202200238 - D. van Gerven, S. Sutorius, J. Bruns, M. S. Wickleder
Stabilizing the Homopolycation (I4)2+ with a Hexasulfate in (I4)[S6O19] and a Borosulfate in (I4)[B(S2O7)2]2
Chemistryopen 2022, 11, e202200122.
10.1002/open.202200122 - S. Sutorius, D. van Gerven, S. Olthof, B. Rasche, J. Bruns
Polycations Stabilised by Borosulfates: [Au3Cl4][B(S2O7)2] and the One-Dimensional Metal [Au2Cl4][B(S2O7)2](SO3)
Chem. Eur. J. 2022, 28, e202200004.
10.1002/chem.202200004 - T. Rennebaum, D. van Gerven, M. S. Wickleder
The Unprecedented [S4N2O10]2− Anion in the Molecular Gold Complexes [Au2Br2(S4N2O10)2] and [Au2Cl2(S4N2O10)2](S2O5Cl2)
Chem. Eur. J. 2022, 28, e202202171.
10.1002/chem.202202171 - J. Nickelsen, D. van Gerven, M. S. Wickleder
In situ single crystal growth of tris(trimethylsilyl)phosphate, (Me3SiO)3PO
Zeitschrift für anorganische und allgemeine Chemie 2022, 648, e202200184.
10.1002/zaac.202200184 - D. van Gerven, M. S. Wickleder
S6N2O15 — A Nitrogen-Poor Sulfur Nitride Oxide, and the Anhydride of Nitrido-tris-Sulfuric Acid
Angew. Chem. Int. Ed. 2020, 59, 17169-17171.
10.1002/anie.202005056 - C. Stoll, D. van Gerven, H. Huppertz
Serendipitous formation of K15NaSn5F36
Z. Naturforsch. B 2020, 75, 309-315.
10.1515/znb-2019-0201 - J. Bruns, D. van Gerven, T. Klüner, M. S. Wickleder
Palladium(IV) in an Oxoanionic Environment: The XeF2 Assisted Synthesis of [Pd(S2O7)3]2−
Angew. Chem. Int. Ed. 2016, 55, 8121-8124.
10.1002/anie.201601767 - F. Brockmeyer, D. van Gerven, W. Saak, J. Martens
Two Sequential Multicomponent Reactions: Synthesis of Thiazolidin-4-yl-1,3,4-oxadiazoles under Mild Conditions
Synthesis 2014, 46, 1603-1612.
10.1055/s-0033-1341043
Talks and Posters
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D. van Gerven, M. S. Wickleder
Tris-(disulfato)-metallate
45. Hirschegg-Festkörperchemiesymposium, Hirschegg (Österreich), 26.05 - 28.05.2016 -
D. van Gerven, M. S. Wickleder
Rotes Palladiumdisulfat
47. Hirschegg-Festkörperchemiesymposium, Hirschegg (Österreich), 31.05. - 03.06.2018 -
D. van Gerven, M. S. Wickleder
XeF2 als Schlüssel zur Synthese von [M(S2O7)3]2- der Platinmetalle (M = Pd, Os, Ir)
18. Fluortag, Schmitten, 2018 -
D. van Gerven, M. S. Wickleder
Über Polyiodkationen und andere positive Überraschungen
48. Hirschegg-Festkörperchemiesymposium, Hirschegg (Österreich), 20.06. - 23.06.2019 -
D. van Gerven, J. Nickelsen, M. S. Wickleder
Crystallizing Trimethylsilyl Derivatives of mineralic acids with a CO2-Laser: Crystal Structures of (Me3SiO)3PO and (Me3SiO)NO2
21st Conference on Inorganic Chemistry, Marburg, 2022.