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Forschungsgebiet

Synthetic Approaches to new Compounds of Rare Earth Elements in their Divalent and Tetravalent Oxidation States

 

Doktorarbeit, Universität zu Köln, AK Wickleder, April 2024

Systematic Studies of Oxoanionic Lanthanoid Salts in their +II and +IV Oxidation States

 

Masterarbeit, Universität zu Köln, AK Wickleder, August 2020

Investigations of Potential Synthetic Approaches to New Pr(IV) Salts

 

Bachelorarbeit, Universität zu Köln, AK Berkessel, 2017

Untersuchungen zum Substratspektrum der titankatalysierten assymmetrischen Epoxidierung

 

Publikationen

6. Niko T. Flosbach, Maxim Bykov, Elena Bykova, Bertold Rasche, Mohamed Mezouar, Timofey Fedotenko, Stella Chariton, Vitali B. Prakapenka, Mathias S. Wickleder
Stabilization of Pr4+ in Silicates – High Pressure Synthesis of PrSi3O8 and Pr2Si7O18
Inorg. Chem. 2024, 63, 11, 4875-4882.

5. Tim Lippold, Axel G. Griesbeck, Robert Herzhoff, Mathias S. Wickleder, Laura Straub, Niko T. Flosbach
5-Chlorocoumaranone-Conjugates as Chemiluminescent Protecting Groups (CLPG) and Precursors to Fluorescent Protecting Groups (FPG)
Photochem 2023, 3(3), 373-389.

4. Thomas Kasperowicz, Niko Flosbach, Dennis Grödler, Hannah Kasperowicz, Jörg-M. Neudörfl, Tobias Rennebaum, Mathias S. Wickleder, Markus Zegke
Solvated Actinoids: Methanol, Ethanol, and Water Adducts of Thorium and Uranium Tetrachloride
Eur. J. Inorg. Chem. 2022, e202200227.

3. Zhifang Guo, Ryan Huo, Yu Qing Tan, Niko T. Flosbach, Nicole Wang, Céline Leonhardt, Aron Urbatsch, Glen B. Deacon, Peter C. Junk, Ekaterina I. Izgorodina, Victoria L. Blair
A new twist on an old molecule: a rotameric isomer of bis(pentafluorophenyl)mercury
J. Coord. Chem. 2021, 74, 2947-2958.

2. Kevin J. Sheehy, Lorraine M. Bateman, Niko T. Flosbach, Martin Breugst, Peter A. Byrne
Competition between N and O: use of diazine N-oxides as a test case for the Marcus theory rationale for ambident reactivity
Chem. Sci. 2020, 11, 9630-9647.

1. Kevin J. Sheehy, Lorraine M. Bateman, Niko T. Flosbach, Martin Breugst, Peter A. Byrne
Identification of N- or O-Alkylation of Aromatic Nitrogen Heterocycles and N-Oxides Using 1H–15N HMBC NMR Spectroscopy
Eur. J. Org. Chem. 2020, 3270-3281.

 

Tagungsbeiträge:

5. Niko Flosbach, Mathias S. Wickleder
High Pressure Synthesis of Pr2O5 - A unique Lanthanoid Oxide Peroxide
11th International Conference on f-elements (ICFE-11), Strasbourg, Frankreich, 2023.

4. Niko Flosbach, Mathias S. Wickleder
"Divalent Lanthanide Triflates" (invited lecture) and "High Pressure Synthesis of Praseodymium Silicates" (Poster)
6th International Conference on the Physics of Optical Materials and Devices, Belgrad, Serbien, 2022.

3. Niko Flosbach, Mathias S. Wickleder
Structure, Magnetism and Luminescence of Eu(OTf)2(MeCN) and Sm(OTf)2(MeCN) (Oral contribution)
Terra Rarae, Leipzig, 2022.

2. Niko Flosbach, Mathias S. Wickleder
Ungewöhnliche Oxidationsstufen von Lanthanoiden in oxoanionischer Umgebung
49. Hirschegg-Seminar Festkörperchemie, Hirschegg, 2022.

1. Niko Flosbach, Mathias S. Wickleder
[Pr(O2C2F3)3(HO2C2F3)2] and [Pr(O2C2F3)3(HO2C2F3)(H2O)] - Two New Praseodymium Trifluoroacetates
GDCh Wissenschaftsforum, online, 29.08. - 01.09.2021